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I don't actually own 2007's White Chalk by Polly Jean Harvey, or better known as PJ Harvey, but I do have her latest 2-track single called The Devil. This was released last month on iTunes as well as 7" and CD single from Universal Music.
I can't say that I like the new song, it doesn't quite have her poppier/guitar pop of "Good Fortune" (from Stories from the City, Stories from the Sea) or her debut single of "Sheela-Na-Gig" (from Dry). Instead, "The Devil" is a falsetto-ey song, backed with some piano. I think they were going for eerie or creepy, and I am not sure what to expect of it. Perhaps if you're in the mood, this might be a great song... otherwise, I suggest checking out her earlier albums.